The Planetary Boundary Layer Height (PBLH) plays an important role in the formation and development of air pollution events. Particulate Matter is one of major pollutants in China. Here, we present the characteristics of PBLH through three-methods of Lidar data inversion and show the correlation between the PBLH and the PM2.5 (PM2.5 with the diameter 75 μg/m3 and the PM2.5 < 35 μg/m3 in daytime, respectively. The low PBLH often occurs with condition of the low wind speed and high relative humidity, which will lead to high PM2.5 concentration and the low visibility. On the other hand, the stability of PBL is enhanced by high PM concentration and low visibility.