Date of Award

Fall 1-2-2026

Document Type

Thesis

Degree Name

Master of Arts (MA)

Department

Chemistry

First Advisor

Hiroshi Matsui

Second Advisor

Dhiman S. Pal

Academic Program Adviser

Yujia Xu

Abstract

Peptide nano-assemblies can regulate cellular pathways in a structure-dependent manner. Here, we show that the enzyme-responsive peptide NapFFK(NBD)Yp forms distinct nanoscale assemblies at different concentrations, triggering differential ER stress and extracellular vesicle release in MDA-MB231 cells. These results highlight the importance of supramolecular organization in peptide–cell interactions.

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